辛纳纳 副教授

E-mail：xinnana@lcu.edu.cn

xinnana2008@163.com

山东省聊城市东昌府区伟德国际betvlctor1946东校区伟德国际1946官网湖南路1号

科研方向：有机合成方法学；富勒烯化学

讲授课程：有机化学（一），有机化学（二）；化学与健康。

教育经历:

2005.09-2009.07 伟德国际betvlctor1946 学士；

2009.09-2014.07 北京大学 博士

科研项目

主持国家自然科学基金青年项目1项，2015.01-2018.12，已结题；

参与国家自然科学基金青年项目1项，2016.01-2019.12，已结题；

主持伟德国际betvlctor1946青年博士启动基金1项，已结题。

论著一览：

         1- Preparation of Vinylphosphonates from Ketones Promoted by Tf2O N. N. Xin*, Y. Lv, Y. Lian, Z. Lin, X.-Q. Huang, C.-Q. Zhao*, and Y. Wang J. Org. Chem. 2023, ASAP. DOI: 10.1021/acs.joc.2c02563.

         2-Markovnikov-addition of H-phosphonates to terminal alkynes under metal- and solvent-free conditions. N. N. Xin*, Y. Lian, Y. Lv, Y. J. Wang, X.-Q. Huang, and C.-Q. Zhao*, RSC Adv., 2021, 11, 24991-24994.

         3-The crystal structure of N,N’-(Disulfanediyldi-2,1-phenylene)di(6’-methylpyridine)-2-carboxamide, C26H22N4O2S2 N. N. Xin, J. Zheng and Q. P. He*, Z. Kristallogr. - N. Cryst. Struct., 2021, 236, 1055-1057.

         4- 不同构象表示法使用Cram规则的探讨 辛纳纳*，龚树文，黄现强 化学教育，2020，41（12），27-30.

         5- A Novel Organic–Inorganic Hybrids Heterometallic Materials: Synthesis and Highly Efficient Conversion of CO2 X. Y. Jiang, H. M. Ding, Y. Liu, H. C. Zhang, N. N. Xin*, Q. P. He* Sci. Adv. Mater. 2019, 11, 203–207.

         6- Controlled synthesis of two pyrazole-3-carboxylic acid mononuclear- and binuclear-Copper complexes and their highly selective oxidation of benzylic sp3 C-H bonds D. D. Zhong, C. X. Li, Y. J. Li, Y. H. Wang, H. C. Zhang, Y. Q. Qi, X. Q. Huang*，N. N. Xin*, D. C. Li*, B. Q. Wang Sci. Adv. Mater. 2019, 11, 223-229.

         7- One-Pot Reaction To Form Hydrophosphorylated Fullerenes from C60 and Ph3–nPCln/ROH N. N. Xin*, X. Y. Xie, C. -Q. Zhao, X. Q. Huang, J. H. Zhang, J. -Y. Du, J. Yang, C. L. Ma, Synlett, 2018, 29(9), 1219-1222.

         8- Fullerene doping: Preparation of azafullerene C59NH and oxafulleroids C59O3 and C60O4, N. N. Xin, H. Huang, J. X. Zhang, Z. F. Dai, L. B. Gan* Angew. Chem. Int. Ed. 2012, 51, 6163 –6166.

         9- Synthesis of C60(O)3: An open-cage fullerene with a ketolactone moiety on the orifice N. N. Xin, X. B. Yang, Z. S. Zhou, J. X. Zhang, S. X. Zhang, L. B. Gan* J. Org. Chem. 2013, 78, 1157−1162.

         10- Metal-Free One-Pot Synthesis of 3-Phosphinoylbenzofurans via Phospha-Michael Addition/Cyclization of H-Phosphine Oxides and in Situ Generated ortho-Quinone Methides J. Y. Du*, Y. H. Ma, R. Q. Yuan, N. N. Xin, S. Z. Nie, C. L. Ma, C. Z. Li, C. Q. Zhao Org. Lett. 2018, 20, 477-480.

         11- Synthesis of Metal Complexes with an Open-Cage Fullerene as the Ligand, Z. S. Zhou, N. N. Xin, L. B. Gan*. Chem. Eur. J. 2018, 24, 451-457.

         12- Three Pd-decavanadates with a controllable molar ratio of Pd to decavanadate and their heterogeneous aerobic oxidation of benzylic C–H bonds, X. Q. Huang*, J. K. Li, G. D. Shen, N. N. Xin, Z. G. Lin, Y. N. Chi, J. M. Dou, D. C. Li, C. W. Hu Dalton Trans. 2018, 47, 726-733.

         13- One-Pot Process That Efficiently Generates Single Stereoisomers of 1,3-Bisphosphinylpropanes Having Five Chiral Centers H. Zhang, Y. M. Sun, Y. L. Zhao, Z. Y. Zhou, J. P. Wang, N. N. Xin, S. Z. Nie, C. Q. Zhao*, L. B. Han. Org. Lett., 2015, 17, 142–145.

         14- Addition of optically pure H-phosphinate to ketones: selectivity, stereochemistry and mechanism, Y. M. Sun, N. N. Xin, Z. Y. Xu, L. J. Liu, F. J. Meng, H. Zhang, B. C. Fu, Q. J. Liang, H. X. Zheng, L. J. Sun, C. Q. Zhao*, L. B. Han Org. Biomol. Chem., 2014, 12, 9457.

         15- Synthesis of an azahomoazafullerene C59N(NH)R and Gas-Phase formation of the diazafullerene C58N2, H. Huang, G. H. Zhang, D. Wang, N. N. Xin, S. S. Liang, N. D. Wang, L. B. Gan* Angew. Chem. Int. Ed. 2013, 52, 5037 –5040.

         16- Bromination-mediated regioselective preparation of cyclopentadienyl-type [60]fullerene derivatives with alkoxy, peroxy, and bromo or hydro addends, J. X. Zhang, N. N. Xin, L. B. Gan* J. Org. Chem. 2011, 76, 1735–1741.

         17- Preparation of ketolactone and bislactone [60]fullerene derivatives and their conversion into open-cage fullerenes with a 12- or 15-membered orifice, J. X. Zhang, F. D. Wang, N. N. Xin, D. Z. Yang, L. B. Gan* Eur. J. Org. Chem. 2011, 5366–5373.

         18- Selective synthesis of fullerenol derivatives with terminal alkyne and crown ether addends, H. Huang, G. Zhang, S. S. Liang, N. N. Xin, L. B. Gan* J. Org. Chem. 2012, 77, 2456−2462.

         19- Facile preparation of fullerenyl boronic esters，Z. F. Dai, Z. P. Jiang, G. Zhang, N. N. Xin, L. B. Gan* Tetrahedron 2012, 68, 5193-5196.

所获奖励：

         山东省青年教师教学比赛三等奖 2021.05.

         伟德国际betvlctor1946青年教师教学比赛一等奖 2020.12

          伟德国际betvlctor1946信息化教学比赛二等奖 2019.12.

          北京大学校长奖学金 2012-2014